Breast stroke is the easiest and usually the first style beginners pick. However, it could increase lower back pain, especially for women who are more naturally prone to them in the first place. Front crawl is more strenuous, and therefore more aerobically effective, and keeps you in better shape (or promotes weight loss if that's what you want).
One way to deal with the back problem in breast stroke is using a snorkel (a tube that sticks out of the water allowing you to breath without taking your head out), thus maintaining a straight back throughout the swim.
The best swimming style is the one you can keep to a regular routine, so basically you should pick the one that's good for you. Whatever you choose will give you a cardiovascular workout.