The lump sum you receive from a structured settlement buyer will have the same tax treatment as your structured settlement annuity. In other words, if your structured settlement payments were tax free then the lump sum you would receive from the sale would be tax free as well.
Most structured settlement annuities qualify for tax free treatment under section 130 of the Internal Revenue Code. The U.S Government has taken several steps to protect tort victims and other parties from unfair taxes that resulted from personal injury settlements.