OK, sorry, I read it again and I see now. My answer was totally inappropriate, I'm going to delete it.
Strangely enough I just had a conversation about that with a friend, it was about the opposite situation in which a guy told his wife after 4 children and a long marriage that he's actually gay and that he kept having relationships with men all through their marriage. He didn't want to be gay and kept trying to deny that part of himself, but eventually he couldn't take it anymore.
The question is this, if she has never been with a woman, it might be just curiosity and wanting to see how it'll be. Then you need to figure out if you can live with the notion of your wife have a one time experience with a woman, I know that for some people this is considered cheating and they will not live with it, some people might be OK with the notion and for some it would be a turn on.
I think your wife's actually being pretty fair with sharing her feelings with you and not just having a go at it behind your back. I think that you should repay with the same fairness and be totally open and honest about what it is you can or can not live with in this situation. This has effect on the relationship, it changes things between the two of you, but it might not be all for the worse. I think that in different way her having the freedom to explore a fantasy might bring her more aware to her sexuality and bring the two of you together.
If you are comfortable with it, the best solution I can think of is a 3som - in which case she gets to be with a woman and you don't get to be left out, she gets to explore her fantasy in the frame of the relationship.