Hi Toni. I don't know the psychology behind his behavior, but if it's really disturbing you, hoist yourself up on the sink one day while he's home and let him see how odd that looks to use the sink as a toilet!
I'll share a weird thing with you too... My husband use to pee in bottles and stashed them under the bathroom sink! Well as you can imagine it freaked me out! I mean to the point that I was afraid to ask him what his malfunction was! So what I did instead was start filling up bottles of my own pee and stashing them under the sink right next to his. I can see how that might sound like a really strange way to handle it, but it worked... he poured them all out and I have never found another one of his pee bottle collections!
Some people's children. 