I do not know this woman, so I cannot speculate as to her motivations and/or whether or not she was sincere in her offer.
What I CAN tell you is that she is an adult. And as such, she is capable of making decisions and determining when enough is enough and when something is 'too much.'
If she made the offer and you believed it was genuine, then I think you should feel free to take her up on it (I am presuming this IS just a mentoring relationship and NOT anything personal and/or illegal).
If she has changed her mind, she should be competent and intelligent enough to say so.
It is a wise person who learns, 'Don't say yes when you want to say no' and 'Nobody can take advantage of you unless you let them.'
Give her the benefit of the doubt - she is old enough to have learned those lessons long ago. If she hasn't, you'll soon find out.