In terms of paperwork within a beauracracy, local "watchdog" groups in democratic countries keep such information. However, their own analysts compile this data, and it generally isn't shared internationally for a central index.
For instance, in Canada, there is the canadian federation of independent business
This group monitors such information, but I have not heard of them providing this information beyond requests from members.
As for employment data, the UN actually has a surprisingly comprehensive list in terms of percentage of employment in comparison to a countries population, and in comparison to the related world region. In addition, they do publish the state expenditure on civil servant wages in comparison to the government's total expenditure. An example: Venezuala .
The World Bank also publishes a full list regarding government effectiveness, which relates again to bureaucracy. It also allows one to do for a world summary or to compare countries within a region, and other methods.
Hope this helps.