Congratulations on the enlargement of the canine family :-)
The young pup may be too weak or he may have had a tougher journey down the birth canal in comparison with his brothers. It is strange the mother doesn't take better care of him, but she might feel his chances are low and therefore prefers not to get attached.
The first thing to do is take him to a vet. You might have to give him some milk substitute because he's too weak to suckle right now, and clearly too weak to fight his brothers for his mother's nipples.
Good luck