Hi there, I'll suggest the following steps.
1. create the accounts say joe and mary
2. copy the contents of
c:\documents and settings\{existingaccount}\desktop to
c:\documents and settings\joe\desktop and
c:\documents and settings\mary\desktop
do the same for c;\documents and settings\{existingaccount}\favourites and you should be fine.
Don't forget God loves you so much He paid the price for your freedom :-) I coulndn't miss telling you that :D