Okay, this answer may show up twice. If that happens, I apologize but my AOL seems to be having a nervous breakdown. That said, let's get to the question.
First, let me commend you on doing the first thing right. Whenever you are introducing any animals to each other in your household, it is always a good idea to give them a chance to scent (smell) each other before they meet for the first time.
That said, in answer to your question, which is two-fold. First, your oldest cat is not reacting to the youngest cat because the oldest cat is very secure in this life. If anything was afoot, senior kitty would already know it. However, you 6-year-old cat has gone from being the youngest child to being the middle child. Tha is not misprint. If you think of your cats in terms of being children, you'll be able to handle them a lot better.
The 6-year-old has had his or her position in the pecking order changed and is reacting to just that. When a cat, that has already been litter trained, starts to spray or pee in other places, they are "marking their territory" and saying to the kitten "stay out of my territory." If you look closely enough as to WHERE the items are that are being peed on, you should be able to see some kind of area being contained.
As for how to correct the problem, I read the other response and can tell you that over time spraying a cat will get their attention and they will mind you. However, the down side to that is: cats are already cautious creatures. If you start spraying the cat with water -- with or without vinegar -- the cat is going to be suspicious of all your actions. Instead of being excited that you just walked into the room and they're going to get some hugs and cuddles, your cats are going to look to see if you have that bottle or gun in your hand first. There are other ways to deal with this problem.
I would separate the 6-year-old from the oldest cat and the youngest cat. Not as a punishment, but as a way for you to give this kitty some extra special love, care, and attention. Take time out of your day to just spend with special kitty in the room. Tummy rubs, cuddles, stroking the hair, will send your kitty into glorious rapture. Not only are you paying attention, but you're doing the things all cats love to have done to them. Equally, get some cat nip. All your kitties will love you until -- well, until the cat nip runs out. In the mean time, though, you will have peace.
I hope this has answered your question and this answer posts this time. By the way, I am not a vet, but my knowledge comes from having over 75 cats in my lifetime.
Merry Meet and Merry Bide
Cheryl