From what I know mineral wool ( AKA "rock wool") is really really unhealthy - it tend to come loose in the air and breathing the particles can cause asthma and other breathing problems as well as being cancerous.
I don't know how much money you are going to spend on this or whether the insulation is exposed or not exposed to people, there are a lot of different materials that can be used like foam, waste paper and basically anything else that's bulked. This is a good simple article about basic ecological materials that can be used as insulators:
http://www.ecologicalhomes.com.au/insulation.htm
I'm not sure this is for sale yet but it sounds pretty good and worth looking into:
http://www.azobuild.com/details.asp?ArticleID=3349
online store that specialized in green materials and offers 2 insulation options:
http://www.greenbuildingstore.co.uk/insulation.php