I'm so jealous of your shoes! They're adorable! I have a few mini-wedges like this- they're a great alternative to flats and make your calves look oh so much better!!
I wear mine contantly during the day (never at night- the cork heel is pretty casual) with jeans and a flowy top and summer dresses. And since it's getting cooler I'm wearing a summer dress over jeans with the mini wedges. it's still a super casual look but very fashionable! I also like wearing jeans with a crisp white shirt and the little wedges- very chic.
good luck!