Not all siblings get a long and sometimes it takes until people get older to start getting along. There are of course the sad situations in which siblings never learn to get along. However, I would just try to respect what he wants from you, whether it's to leave him alone or to help him with something, whatever. Try to get on his good side, and when he starts being an ass to you, remind him nicely of the nice things you've done for him. Try to just have nice interactions and to avoid the situations in which you guys don't get along well. Be considerate and hopefully he will reciprocate. Good luck.